Ron B. Davis Jr.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
Chromatography - in which partitioning between stationary and mobile phases leads to predictable rates of movement for compounds - is one of the most powerful separation techniques ever developed. And, when done properly, it allows chemists to isolate almost anything they can imagine. Witness a technique at the core of Professor Davis's laboratory experience.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
The energy stored in chemical bonds pales next to the energy holding atomic nuclei together. Look back to the gradual unlocking of the secrets of the nucleus, the discovery of radiation emanating from elements such as uranium, and the eventual harnessing of this phenomenon for weapons, electrical power, and medical treatments.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Revisit the nuclear energy binding curve, noting that most elements lighter than iron can release energy by fusing together. This is an even more energetic reaction than fission, and it is what powers the sun. Follow the development of fusion weapons and the so-far-unrealized dream of fusion reactors.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
Probe the connections between biology and metals with this lecture on some compounds and reactions in the field of organometallic chemistry. As you'll quickly learn, organometallics have a range of practical applications; one example you'll encounter is Dotarem, an organometallic compound used to help detect tumors in cancer patients.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Stoichiometry may sound highly technical, but it is simply the relative proportions in which chemicals react. Discover how to balance a reaction equation, and learn how to solve problems involving limiting reagents, theoretical yield, percent yield, and optimized reactions.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Meet one of the fathers of modern physical chemistry, Linus Pauling. Hear about his theory of orbital hybridization, which solves some of the shortcomings of VSEPR theory by averaging the charge of electrons in different orbitals, accounting for the peculiar geometry of certain molecules.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
Start taking a more biologically oriented look at the foundations of organic chemistry by investigating compounds known as carbohydrates. Examine Fischer projections of their two main classes, aldoses and ketoses; learn how cyclic sugars help create disaccharides and polysaccharides used in everything from fruit preserves to body armor; and more.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
In this final lecture on spectroscopic techniques, discover the importance of modern NMR spectrometers, which use superconducting magnets and radio receivers to collect spectra with more speed and precision (and in different ways) than other techniques. Also, get an intriguing lesson in the human element - and limitations - involved in spectroscopy.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Probe the methods used by researchers to create molecules that can correct medical problems such as inflammation, bacterial infections, and cancer. As an example, study the lock-and-key model of enzyme activity, which explains how many enzymes work, highlighting a potential weak link that can be exploited by drugs.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Return to the periodic table, introduced in Lecture 1, to practice predicting properties of elements based on their electronic structure. Then, witness what happens when three different alkali metals react with water. Theory forecasts a pronounced difference in the result. Is there?
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Dig deeper into the nucleus to discover how so little matter can convert into the tremendous energy of a nuclear explosion, as described by Albert Einstein's famous mass-energy equation. Focus on nuclear binding energy and mass defect, both of which are connected to the release of nuclear energy.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
Complete your mastery of the trifecta of fundamental organic reactions with a lecture on addition, which adds new groups to unsaturated molecules by sacrificing pi bonds for more stable sigma bonds. You'll explore the basics of addition reactions; the hydrogenation of alkenes and alkines; the ways addition has helped create food additives; and much more.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
Investigate some of the key methods scientists employ to communicate the right structural information about molecular compounds, including their identity, the ratio of elements that comprise them, and their connectivity. Explore Fischer projections, Newman projections, and stereoimages - all of which help us overcome the challenges of conveying the three-dimensional positions of atoms.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
How do organic chemists actually prove the behavior of molecules and chemical structures you've learned about in the preceding lectures? The answer: spectroscopy, which entails the observation of the interaction between matter and light. In the first of several lectures on the topic, focus specifically on observations made with the UV-visible spectrum.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Now turn to liquids, which have a more complicated behavior than gases. The same intermolecular forces apply to both, but at much closer range for liquids. Explore the resulting properties, including viscosity, volatility, incompressibility, and miscibility. Also consider applications of these qualities.
Publisher
The Great Courses
Pub. Date
2014.
Language
English
Description
Visit the radio portion of the electromagnetic spectrum for insights into how tiny, atom-sized magnets in organic molecules interact with radio waves (and each other) to produce a complex set of magnetic resonances - which are one of the gold-standard identification tools used in modern organic chemistry. Topics include Zeeman splitting, magnetic spin-spin coupling, and multiplets.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Encounter reduction-oxidation (redox) reactions, which involve the exchange of electrons between substances. Discover that this process explains geological events on the early Earth, including why iron in its metallic state is so rare in nature. Then explore associated phenomena, including the activity series of metals.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Apply the physics of moving bodies to the countless particles comprising a gas. Observe how Graham's law links the mass of gas particles to the rate at which they escape through a small aperture, a process known as effusion. See how this technique was used to enrich uranium for the first atomic weapons.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
Now turn to the chemistry of the atmosphere, in particular the 1% composed of gases other than nitrogen and oxygen. Map the structure of the atmosphere, charting its temperature profile. Hear the good and bad news about ozone, and probe the cause of acid rain.
Publisher
The Great Courses
Pub. Date
2016.
Language
English
Description
In the first of two lectures on the properties of gases, review the basic equations that describe their behavior. Learn the history of Boyle's law, Gay-Lussac's law, Charles's law, and Avogadro's law. Then use these four expressions to derive the celebrated ideal gas law.